Synthesis of new nano Schiff base complexes: X-ray crystallography, thermal, electrochemical and anticancer studies of nano uranyl Schiff base complexes

Bulletin of The Chemical Society of Ethiopia

F. D. Firuzabadi¹ 

关键词: Uranyl Schiff base complex;    Anticancer activities;    Thermal studies;    Electrochemistry;    X-ray crystallography;   

DOI  :  10.4314/bcse.v32i1.8

学科分类：化学（综合）

来源: Chemical Society of Ethiopia

【 摘 要 】

This study presents synthesis and characterization of new nano uranyl Schiff base complexes. Electrochemistry of these complexes showed a quasireversible redox reaction without any successive reactions. Furthermore, X-ray crystallography exhibited that beside the coordination of tetradentate Schiff base, one solvent molecule (dimethylformamide) was also coordinated. According to Coats-Redfern plots the kinetics of thermal decomposition of the studied complexes was first-order in all stages. Anticancer activities of the uranyl Schiff base complexes against cancer cell lines (Jurkat) was studied and determined by MTT (3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazoliumbromide) assay. The results demonstrated that the complexes with aliphatic bridging units showed less anticancer activities than those having the aromatic units.

【 授权许可】

Unknown