Kinetic analysis of high nitrogen energetic materials using multivariate non-linear regression.

Campbell, M. S.

Technical Information Center Oak Ridge Tennessee

关键词: Chemical reaction kinetics;    Regression analysis;    Nonlinear problems;    Kinetics;    Nitro compounds;   

RP-ID  :  DE2001783687

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

New high-nitrogen energetic materials were synthesized by Hiskey and Naud. J. Opfermann reported a new tool for finding the probable model of the complex reactions using multivariate non-linear regression analysis of DSC and TGA data from several measurements run at different heating rates. This study is to take the kinetic parameters from the different steps and discover which reaction step is responsible for the runaway reaction by comparing predicted results from the Frank-Kamenetsckii equation with the critical temperature found experimentally using the modified Henkin test.