Fractional kinetics of photocatalytic degradation

Journal of Advanced Dielectrics

C. L. Wang¹ 

[1] School of Physics, Shandong University, Jinan, Shandong 250100, P. R. China;

关键词: Chemical reaction kinetics;    photocatalytic materials;    fractional calculus;   

DOI  :  10.1142/S2010135X18500340

来源: DOAJ

【 摘 要 】

In this paper, photocatalytic degradation processes of different materials are fitted to the first-order kinetic model, second-order kinetic model and fractional first-order kinetic model. Deterministic coefficients are calculated for the evaluation of the validity of these models. The fitting results show clearly that the degradation process can fit the fractional first-order kinetic model in a very good manner. In this way, two material parameters can be well defined. One is the degradation time, which can be used to describe the photocatalytic degradation process quantitatively. Another is the order of the derivative, which could be related to the material’s microstructure.

【 授权许可】

Unknown