Significant surface flattening effect by Au addition for Cu growth on Cu3Au(001)

SURFACE SCIENCE

卷:619

Article

Kojima, Takayuki¹  Mizuguchi, Masaki¹  Takanashi, Koki¹ 

[1] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

关键词: Epitaxial growth;    Flat film;    Cu;    Au;    Surface segregation;    Surfactant;   

DOI  :  10.1016/j.susc.2013.09.021

来源: Elsevier

【 摘 要 】

To prepare a flat surface of Cu film on Cu3Au(001), we utilized the effect of Au addition to Cu, and investigated the dependence of the growth mode on the amount of Au added. We grew Cu-x%Au (x = 0-20) films on Cu3Au(001) underlayers by co-deposition and observed the surface morphology by scanning tunneling microscopy. For Cu film without Au addition, three-dimensional islands were observed on the surface while flat two-dimensional surfaces were observed for Cu film with only 2.5%Au addition. This difference in the growth mode was found to be due to surface segregation of Au revealed by in situ Auger electron spectroscopy. It was considered that the Au atoms acted like a surfactant and avoided three-dimensional island growth by suppression of the accumulation of epitaxial strain in Cu-x%Au films. However, the terrace size decreased with x. This decrease was thought to be due to an increase in an effective Ehrlich-Schwoebel barrier. The surface flattening effect by addition of another element would be obtained in other systems as well by employing a suitable element. (C) 2013 Elsevier B.V. All rights reserved.

【 授权许可】

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