期刊论文详细信息
Green Processing and Synthesis | 卷:6 |
Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene | |
Nikoshvili Linda Zh.1  Rebrov Evgeny V.2  Matveeva Valentina G.2  Sulman Alexandrina2  Sulman Esther M.2  Bykov Alexey V.2  Protsenko Igor I.2  | |
[1] Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026 Tver, Russia, Tel.: +74822789348, Fax: +74822789317; | |
[2] Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, Russia; | |
关键词: gamma-valerolactone; hydrogenation; hypercrosslinked polystyrene; levulinic acid; ruthenium nanoparticles; | |
DOI : 10.1515/gps-2016-0189 | |
来源: DOAJ |
【 摘 要 】
This work is devoted to the investigation of the possibility of the use of Ru-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in the hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL). HPS-based Ru-containing catalysts were synthesized at variation of HPS type (MN100 bearing amino groups or MN270 without functional groups) and metal content. Catalyst 5%-Ru/MN100 was shown to compete with commercial 5%-Ru/C and to allow carrying out the hydrogenation of LA in aqueous medium with high yields of GVL (more than 99%).
【 授权许可】
Unknown