Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene

Green Processing and Synthesis

卷:6

Nikoshvili Linda Zh.¹  Rebrov Evgeny V.²  Matveeva Valentina G.²  Sulman Alexandrina²  Sulman Esther M.²  Bykov Alexey V.²  Protsenko Igor I.² 

[1] Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026 Tver, Russia, Tel.: [phone], Fax: [phone];

[2] Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina str. 22, 170026Tver, Russia;

关键词: gamma-valerolactone;    hydrogenation;    hypercrosslinked polystyrene;    levulinic acid;    ruthenium nanoparticles;   

DOI  :  10.1515/gps-2016-0189

来源: DOAJ

【 摘 要 】

This work is devoted to the investigation of the possibility of the use of Ru-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in the hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL). HPS-based Ru-containing catalysts were synthesized at variation of HPS type (MN100 bearing amino groups or MN270 without functional groups) and metal content. Catalyst 5%-Ru/MN100 was shown to compete with commercial 5%-Ru/C and to allow carrying out the hydrogenation of LA in aqueous medium with high yields of GVL (more than 99%).

【 授权许可】

Unknown