期刊论文详细信息
Green Processing and Synthesis | |
Hydrogenation of levulinic acid using Ru-containing catalysts based on hypercrosslinked polystyrene | |
article | |
Igor I. Protsenko1  Linda Zh. Nikoshvili1  Alexey V. Bykov1  Valentina G. Matveeva1  Alexandrina Sulman1  Esther M. Sulman1  Evgeny V. Rebrov1  | |
[1] Department of Biotechnology and Chemistry, Tver Technical University | |
关键词: gamma-valerolactone; hydrogenation; hypercrosslinked polystyrene; levulinic acid; ruthenium nanoparticles; | |
DOI : 10.1515/gps-2016-0189 | |
来源: De Gruyter | |
【 摘 要 】
This work is devoted to the investigation of the possibility of the use of Ru-containing catalysts on the basis of polymeric matrix of hypercrosslinked polystyrene (HPS) in the hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL). HPS-based Ru-containing catalysts were synthesized at variation of HPS type (MN100 bearing amino groups or MN270 without functional groups) and metal content. Catalyst 5%-Ru/MN100 was shown to compete with commercial 5%-Ru/C and to allow carrying out the hydrogenation of LA in aqueous medium with high yields of GVL (more than 99%).
【 授权许可】
CC BY
【 预 览 】
Files | Size | Format | View |
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RO202107200001723ZK.pdf | 641KB | download |