Techno-economic Analysis for the Thermochemical Conversion of Lignocellulosic Biomass to Ethanol via Acetic Acid Synthesis

Zhu, Yunhua ; Jones, Susanne B.

关键词: ACETIC ACID;    BIOMASS;    CARBON MONOXIDE;    ECONOMICS;    ETHANOL;    FUEL SUPPLIES;    GASIFICATION;    HYDROGEN;    HYDROGENATION;    LIQUID FUELS;    MARKET;    METHANOL;    METRICS;    PRICES;    SECURITY;    SYNTHESIS;    WOOD Biomass;    gasification;    ethanol;    acetic acid;    hydrogenation;    economics;   

DOI  :  10.2172/962851
RP-ID  :  PNNL-18483
PID  :  OSTI ID: 962851
Others  :  Other: BM0101010
Others  :  TRN: US200917%%128

美国|英语

来源: SciTech Connect

【 摘 要 】

Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). This study performs a techno-economic analysis of the thermo chemical conversion of biomass to ethanol, through methanol and acetic acid, followed by hydrogenation of acetic acid to ethanol. The conversion of syngas to methanol and methanol to acetic acid are well-proven technologies with high conversions and yields. This study was undertaken to determine if this highly selective route to ethanol could provide an already established economically attractive route to ethanol. The feedstock was assumed to be wood chips at 2000 metric ton/day (dry basis). Two types of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. Process models were developed and a cost analysis was performed. The carbon monoxide used for acetic acid synthesis from methanol and the hydrogen used for hydrogenation were assumed to be purchased and not derived from the gasifier. Analysis results show that ethanol selling prices are estimated to be $2.79/gallon and $2.81/gallon for the indirectly-heated gasifier and the directly-heated gasifier systems, respectively (1stQ 2008$, 10% ROI). These costs are above the ethanol market price for during the same time period ($1.50 - $2.50/gal). The co-production of acetic acid greatly improves the process economics as shown in the figure below. Here, 20% of the acetic acid is diverted from ethanol production and assumed to be sold as a co-product at the prevailing market prices ($0.40 - $0.60/lb acetic acid), resulting in competitive ethanol production costs.