Enantioselective Hydrogenations with Chiral Titanocenes

Molecules

Oleksiy Vassylyev¹  Anthony Panarello¹ 

[1] id="af1-molecules-10-00587">Department of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ 08854-8058, USA. Tel.: [phone], Fax: [phone]

关键词: Titanocenes;    hydrogenation;    alkenes;    imines;    ketones;   

DOI  :  10.3390/10060587

来源: mdpi

【 摘 要 】

In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of enantioselectivity and the hydrogenation mechanisms are reviewed as well. Catalyst immobilization and the different immobilization techniques are examined.

【 授权许可】

Unknown   
© 2005 by MDPI (http://www.mdpi.org).