Electrochemical Studies of the LiFePO4 Thin Films prepared with Pulsed Lasser Deposition.

Song, S. W. ; Reade, R. P. ; Striebel, K. A.

Technical Information Center Oak Ridge Tennessee

关键词: Electrochemistry;    Thin films;    Lasers;    Energy storage;    Electrodes;   

RP-ID  :  DE2004822962

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

Thin films of LiFePO4 have been prepared on stainless steel substrates with pulsed laser deposition utilizing an Ar atmosphere. Films were characterized with XRD, SEM, Raman spectroscopy and electrochemistry in liquid electrolyte. Raman spectral analysis revealed the presence of carbon in the films, even though the targets contained less than a few percent residual carbon. The Raman spectra also suggest the presence of various iron oxide species on the surface of the film. The 75nm film showed reversible cycling of more than 90 mAh/g for 60 cycles and a coulombic efficiency close to 1. Variable sweep rate cyclic voltammetry showed a diffusion-controlled reaction with an effective diffusivity of about 10-12 cm2/s. The performance of the thicker film was poor with a coulombic efficiency much less than 1.