Field-structured composite studies.

Martin, James Ellis ; Williamson, Rodney L.

Sandia National Laboratories

关键词: Electric Conductivity.;    Shrinkage Composite Materials.;    Nickel;    Gold;    Polymers;   

DOI  :  10.2172/918752
RP-ID  :  SAND2004-1291
RP-ID  :  AC04-94AL85000
RP-ID  :  918752

美国|英语

来源: UNT Digital Library

【 摘 要 】

Field-structured composites (FSCs) were produced by hosting micron-sized gold-coated nickel particles in a pre-polymer and allowing the mixture to cure in a magnetic field environment. The feasibility of controlling a composite's electrical conductivity using feedback control applied to the field coils was investigated. It was discovered that conductivity in FSCs is primarily determined by stresses in the polymer host matrix due to cure shrinkage. Thus, in cases where the structuring field was uniform and unidirectional so as to produce chainlike structures in the composite, no electrical conductivity was measured until well after the structuring field was turned off at the gel point. In situations where complex, rotating fields were used to generate complex, three-dimensional structures in a composite, very small, but measurable, conductivity was observed prior to the gel point. Responsive, sensitive prototype chemical sensors were developed based on this technology with initial tests showing very promising results.