ANALYSIS OF THE LEACHING EFFICIENCY OF INHIBITED WATER AND TANK 23H SIMULANT IN REMOVING RESIDUES ON TANK 48H WALLS

Fondeur, F ; Thomas02 White, T ; Lawrence Oji, L ; Chris Martino, C ; Bill Wilmarth, B

Savannah River Site (S.C.)

关键词: Leaching;    Nitrates;    Thickness;    Organic Boron Compounds;    Oxalates;   

DOI  :  10.2172/891675
RP-ID  :  WSRC-TR-2006-00135
RP-ID  :  DE-AC09-96SR18500
RP-ID  :  891675

美国|英语

来源: UNT Digital Library

【 摘 要 】

Solid residues on two sets of thermowell pipe samples from the D2 riser in SRS Tank 48H were characterized. The residue thickness was determined using the ASTM standard D 3483-05 and was found to be three order of magnitudes below the 1mm thickness estimated from an earlier video of the tank cooling coil inspection. The actual estimated thickness ranged from 4 to 20.4 microns. The mass per unit area ranged from 1 to 5.3 milligrams per square inch. The residues appear to consist primarily of potassium tetraphenylborate (39.8 wt% KTPB) and dried salt solution (33.5 wt% total of nitrates, nitrites and oxalate salts), although {approx}30% of the solid mass was not accounted for in the mass balance. No evidence of residue buildup was found inside the pipe, as expected. The residue leaching characteristics were measured by placing one pipe in inhibited water and one pipe in DWPF Recycle simulant. After soaking for less than 4 weeks, the inhibited water was 95.4% effective at removing the residue and the DWPF Recycle simulant was 93.5% effective. The surface appearance of the pipes after leaching tests appeared close to the clean shiny appearance of a new pipe. Total gamma counts of leachates averaged 48.1 dpm/ml, or an equivalent of 2.35E-11 Ci/gm Cs-137 (dry solids basis), which is much lower than the 1.4 E-03 Ci/gm expected for Tank 48 dry slurry solids.