Nuclear Melt Glass Dissolution and Secondary Mineral Precipitation at 40 to 200C

Zavarin, M ; Roberts, S ; Viani, B ; Pawloski, G ; Rose, T

Lawrence Livermore National Laboratory

关键词: Source Terms;    38 Radiation Chemistry, Radiochemistry, And Nuclear Chemistry;    Dissolution;    58 Geosciences;    Glass;   

DOI  :  10.2172/15014339
RP-ID  :  UCRL-TR-204870
RP-ID  :  W-7405-ENG-48
RP-ID  :  15014339

美国|英语

来源: UNT Digital Library

【 摘 要 】

Most long-lived radionuclides associated with an underground nuclear test are initially incorporated into melt glass and become part of the hydrologic source term (HST) only upon their release via glass dissolution (Pawloski et al., 2001). As the melt glass dissolves, secondary minerals precipitate. The types of secondary minerals that precipitate influence the water chemistry in and around the melt glass. The secondary minerals also provide a sorption sink to the released radionuclides. The changing water chemistry affects the rate of glass dissolution; it also affects the sorption behavior of the released radionuclides. This complex nature of glass dissolution and its important role in defining the HST requires a thorough understanding of glass dissolution and secondary mineral precipitation. The identity of secondary minerals formed at temperatures from 40 to 200 C are evaluated in this report to assist in that understanding.