High temperature Mn2O3/Mn3O4 and Co3O4/CoO systems for thermo-chemical energy storage

JOURNAL OF ENVIRONMENTAL MANAGEMENT

卷:267

Article

Liu, Jia^1,2  Baeyens, Jan²  Deng, Yimin³  Wang, Xianlu⁴  Zhang, Huili¹ 

[1] Beijing Univ Chem Technol, Coll Life Sci & Technol, 15 Beisanhuan East Rd, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, 15 Beisanhuan East Rd, Beijing 100029, Peoples R China

[3] KULeuven KUL, Dept Chem Engn, Proc & Environm Technol Lab, J De Nayerlaan 5, B-2860 St Katelijne Waver, Belgium

[4] Hualu Engn Technol Co Ltd, Hualu Bldg,7 Tangyan South Rd, Xian 710065, Shanxi, Peoples R China

关键词: Mn2O3 and Co3O4;    Ultrafine particles;    BET surface Area and pore characteristics;    Thermo-chemical energy storage;    Reversible redox reaction;    Kinetics;    Reaction reversibility;   

DOI  :  10.1016/j.jenvman.2020.110582

来源: Elsevier

【 摘 要 】

A major action to reduce CO2 emissions is replacing fossil fuels by renewable energy sources. Matching the energy supply and demand by the mostly intermittent renewable resources (wind, solar, wave) is hence a hot topic, and energy storage has become crucial. Thermo-chemical energy storage (TCES) has a higher energy density than sensible and latent heat storage, and allows energy to be stored in the reaction products for multiple reuse and even off-site application. Design parameters are the equilibrium temperature, the reaction heat and the reaction rate, as obtained from both thermodynamic and kinetic assessments. Equilibrium temperatures of the selected metal oxides, Mn2O3/Mn3O4 and Co3O4/CoO are between 1115 K and 1179 K. The present research studies both redox reactions as examples. Commercial Mn2O3 and Co3O4 were previously investigated in detail, and suffer from incomplete reversibility. The present study investigates the use of self-made Mn2O3 and Co3O4 mesoporous particles, of micrometer or nanometer scale, respectively. The average particle size of self-made Mn2O3 particles is < 5 mu m with a BET surface area of 239.7 m(2)/g, and T-eq of 1177 K at ambient pressure. Self-made Co3O4 was of nano size, with average size of about 100 nm, a BET surface area of 54.2 m(2)/g, and T-eq of 1109 K at ambient pressure. The redox reactions of these ultrafine particles are fast and nearly fully reversible. The effect of adding inert Al2O3 or Fe2O3 was also studied, but proven to offer no kinetic benefit, while reducing the reaction heat due to their inert additive character. The findings were used in the design of a 10 kW TCES pilot plant that is currently being tested in a concentrated solar furnace.

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