Co- and Ce/Co-coated ferritic stainless steel as interconnect material for Intermediate Temperature Solid Oxide Fuel Cells

JOURNAL OF POWER SOURCES

卷:343

Article

Falk-Windisch, Hannes¹  Claquesin, Julien¹  Sattari, Mohammad¹  Svensson, Jan-Erik¹  Froitzheim, Jan¹ 

[1] Chalmers, Dept Chem & Chem Engn, Div Energy & Mat, Kemivagen 10, SE-41296 Gothenburg, Sweden

关键词: Interconnect;    Solid oxide fuel cell;    Corrosion;    Cr vaporization;    Area specific resistance;    Coating;   

DOI  :  10.1016/j.jpowsour.2017.01.045

来源: Elsevier

【 摘 要 】

Chromium species volatilization, oxide scale growth, and electrical scale resistance were studied at 650 and 750 degrees C for thin metallic Co- and Ce/Co-coated steels intended to be utilized as the interconnect material in Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFC). Mass gain was recorded to follow oxidation kinetics, chromium evaporation was measured using the denuder technique and Area Specific Resistance (ASR) measurements were carried out on 500 h pre-exposed samples. The microstructure of thermally grown oxide scales was characterized using Scanning Electron Microscopy (SEM), Scanning Transmission Electron Microscopy (STEM), and Energy Dispersive X-Ray Analysis (EDX). The findings of this study show that a decrease in temperature not only leads to thinner oxide scales and less Cr vaporization but also to a significant change in the chemical composition of the oxide scale. Very low ASR values (below 10 m Omega cm(2)) were measured for both Co- and Ce/Co-coated steel at 650 and 750 degrees C, indicating that the observed change in the chemical composition of the Co spinel does not have any noticeable influence on the ASR. Instead it is suggested that the Cr2O3 scale is expected to be the main contributor to the ASR, even at temperatures as low as 650 degrees C. (C) 2017 The Author(s). Published by Elsevier B.V.

【 授权许可】

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