Structural evolution of one-dimensional spin-ladder compounds Sr14-xCaxCu24O41 with Ca doping and related evidence of hole redistribution

Article

关键词: COMPOSITE CRYSTAL-STRUCTURES;    TRUE SATELLITE REFLECTIONS;    SR14CU24O41;    PRESSURE;    SUPERCONDUCTIVITY;    DYNAMICS;    PHASES;    CHARGE;   

DOI  :  10.1103/PhysRevB.84.144111

来源: SCIE

【 摘 要 】

Incommensurate crystal structures of spin-ladder series Sr14-xCaxCu24O41 (x = 3, 7, 11, and 12.2) were characterized by powder neutron scattering method and refined using the superspace group Xmmm(00 gamma)ss0 [ equivalent to superspace group Fmmm(0, 0, 1 + gamma)ss0; X stands for nonstandard centering (0, 0, 0, 0), (0, 1/2, 1/2, 1/2), (1/2, 1/2, 0, 0), (1/2, 0, 1/2, 1/2)] with a modulated structure model. The Ca doping effects on the lattice parameters, atomic displacement, Cu-O distances, Cu-O bond angles, and Cu bond valence sum were characterized. The refined results show that the CuO4 planar units in both chain and ladder sublattices become closer to square shape with an increase of Ca doping. The Cu bond valence sum calculation provided new evidence for the charge transfer from the chains to ladders (approximately 0.16 holes per Cu from x = 0 to 12.2). The charge transfer was attributed to two different mechanisms: (a) the Cu-O bond distance shrinkage on the ladder and (b) increase of the interaction between two sublattices, resulting in Cu-O bonding between the chains and ladders. The low-temperature structural refinement resulted in the similar conclusion with a slight charge backflow to the chains.

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