Dinuclear Lanthanide (III) Coordination Polymersin a Domino Reaction

Inorganics

Geoffrey R. Akien¹  George E. Kostakis²  Alaa Abdul-Sada²  Edward Loukopoulos²  Kieran Griffiths²  Nikolaos Kourkoumelis³ 

[1] Department of Chemistry, Lancaster University, Lancaster LA1 4YB, UK;Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK;Department of Medical Physics, School of Health Sciences, University of Ioannina,45110 Ioannina, Greece;

关键词: coordination polymers;    lanthanide;    single crystal;    89Y-NMR;    catalysis;    domino reaction;   

DOI  :  10.3390/inorganics3040448

来源: DOAJ

【 摘 要 】

A systematic study was performed to further optimise the catalyticroom-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. For this purpose, a seriesof dinuclear lanthanide (III) coordination polymers were synthesised using a dianionicSchiff base and their catalytic activities were investigated.

【 授权许可】

Unknown