Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Molecules

Yuheng Deng¹  Hao Liu¹  Bo Yu¹ 

[1] Department of Chemistry, Capital Normal University, No. 105, Xisanhuan Beilu, Haidian District, Beijing, 100048, China

关键词: multifunctional ligands;    azole-containing carboxylic acids;    coordination polymers;    topology;   

DOI  :  10.3390/molecules15053478

来源: mdpi

【 摘 要 】

This paper provides a brief review of recent progress in the field of metal coordination polymers assembled from azole-containing carboxylic acids and gives a diagrammatic summary of the diversity of topological structures in the resulting infinite metal-organic coordination networks (MOCNs). Azole-containing carboxylic acids are a favorable kind of multifunctional ligand to construct various metal complexes with isolated complexes and one, two and three dimensional structures, whose isolated complexes are not the focus of this review. An insight into the topology patterns of the infinite coordination polymers is provided. Analyzed topologies are compared with documented topologies and catalogued by the nature of nodes and connectivity pattern. New topologies which are not available from current topology databases are described and demonstrated graphically.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.