Dinuclear Lanthanide (III) Coordination Polymers in a Domino Reaction

Inorganics

Edward Loukopoulos²  Kieran Griffiths²  Geoffrey R. Akien¹  Nikolaos Kourkoumelis⁴  Alaa Abdul-Sada²  George E. Kostakis²  Stephen Mansell³ 

[1] Department of Chemistry, Lancaster University, Lancaster LA1 4YB, UK;Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK; E-Mails:Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK;;Department of Medical Physics, School of Health Sciences, University of Ioannina, 45110 Ioannina, Greece; E-Mail:

关键词: coordination polymers;    lanthanide;    single crystal;    ⁸⁹Y-NMR;    catalysis;    domino reaction;   

DOI  :  10.3390/inorganics3040448

来源: mdpi

【 摘 要 】

A systematic study was performed to further optimise the catalytic room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. For this purpose, a series of dinuclear lanthanide (III) coordination polymers were synthesised using a dianionic Schiff base and their catalytic activities were investigated.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.