Supramolecular Coordination Polymers by Self-assembling of Bis-monodentate Ligands with HgI2

International Journal of Molecular Sciences

Xiaokang Li¹  Xiaolin Fan¹ 

[1] Gannan Normal University, Ganzhou, 341000, JiangXi, People’s Republic of China

关键词: Hg(II) complex;    coordination polymers;    bis[4-(4-pyridylmethyleneamino)- phenyl] ether;    N;    N′-bis(3-pyridylmethyl)-diphthalic diimide;   

DOI  :  10.3390/i8010029

来源: mdpi

【 摘 要 】

Two supramolecular coordination polymers, [HgI₂(L¹)·0.5H₂O]_∞ (1) and [HgI₂(L²)·0.4CH₃OH]_∞ (2), have been prepared by ligands L¹ (L¹ = bis[4-(4- pyridylmethyleneamino)phenyl] ether) and L² (L² = N,N′-bis(3-pyridylmethyl)-diphthalic diimide) with HgI₂, respectively. 1 formed an interestingly infinite cross-linked double helical structure, whereas 2 formed the one-dimensional zigzag chains, which are parallel with each other.

【 授权许可】

Unknown   
© 2007 by MDPI