2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate

Molbank

Motohiro Sonoda¹  Kei Mihara²  Tomokazu Saeki²  Akihiro Nomoto²  Vu Thai Hung²  Akiya Ogawa²  Shintaro Kodama²  Yuki Yamamoto² 

[1] Department of Applied Biosciences, Graduate School of Life and Environmental Sciences, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan;Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan;

关键词: alkyne;    benzoyl peroxide;    diselenide;    addition reaction;    oxidation reaction;   

DOI  :  10.3390/M1283

来源: DOAJ

【 摘 要 】

2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-oxo-2-(p-tolyl)acetate was synthesized via the reaction of p-tolylacetylene with diphenyl diselenide and benzoyl peroxide in benzene under atmospheric conditions. The molecular structure of the synthesized compound was evaluated using single-crystal X-ray analysis and spectral analyses. The process reported here provides a rare example of the direct and selective transformation of a terminal alkyne to the corresponding geminal diseleno-substituted alkene.

【 授权许可】

Unknown