Cohalogenation of alkenes with DMF: an easy vicinal haloformyloxylation reaction

Journal of the Brazilian Chemical Society

Adriana V. A. De Souza¹  Gabriela F. Mendonça¹  Rafael B. Bernini¹  Marcio C. S. De Mattos¹ 

关键词: addition reaction;    alkenes;    halogenation;    esters;    beta-haloformyloxylation;   

DOI  :  10.1590/S0103-50532007000800020

来源: SciELO

【 摘 要 】

The reaction of alkenes with trichloroisocyanuric acid or N-bromosaccharin or I2 / Fe2(SO4)3 in the presence of DMF followed by aqueous work-up led to the corresponding beta-haloformate in high regio- and stereoselectivity.

【 授权许可】

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