Crystal structure and Hirshfeld-surface analysis of (benzenecarbothioamide-κS)bromidobis(triphenylphosphane-κP)silver(I)

Acta Crystallographica Section E: Crystallographic Communications

Chaveng Pakawatchai¹  Saowanit Saithong¹  Wattana Ruangwut¹ 

[1] Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;

关键词: crystal structure;    AgI complex;    benzenecarbothioamide;    triphenylphosphane;    hydrogen bonding;    Hirshfeld surface;    supramolecular interaction;   

DOI  :  10.1107/S2056989016009518

来源: DOAJ

【 摘 要 】

The title complex, [AgBr(C7H7NS)(C18H15P)2], was obtained from the reaction of silver(I) bromide with benzenecarbothioamide (C7H7NS) and triphenylphosphane (C18H15P) in the mixed solvent of acetonitrile and ethanol. The mononuclear complex exhibits a distorted tetrahedral coordination geometry about the metal atom, arising from one S atom of a benzenecarbothioamide ligand, two P atoms of two triphenylphosphane molecules and one bromide ion. An intramolecular N—H...Br hydrogen bond is observed and in the crystal structure, inversion dimers linked by pairs of N—H...Br and C—H...Br hydrogen bonds are observed. In addition, C—H...π interactions occur, leading to [101] chains. Hirshfeld-surface analyses are presented and discussed.

【 授权许可】

Unknown