Crystal structure of bis(thiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate

Acta Crystallographica Section E: Crystallographic Communications

Saeed Ahmad¹  Muhammad Amir Nadeem¹  Sidra Nawaz¹  Bushra Mehmood¹  Muhammad Nawaz Tahir² 

[1] Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan;Department of physics, University of Sargodha, Sargodha, Punjab, Pakistan;

关键词: crystal structure;    thiourea;    triphenylphosphane;    silver(I) complex;    hydrogen bonding;   

DOI  :  10.1107/S2056989015001395

来源: DOAJ

【 摘 要 】

In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C—H...O, C—H...S, N—H...O and N—H...S hydrogen bonds, generating (10-1) sheets.

【 授权许可】

Unknown