(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate

Acta Crystallographica Section E

Chaveng Pakawatchai¹  Saowanit Saithong¹  Sofia Mekarat² 

[1] Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;Faculty of Science and Technology, Princess of Naradhiwas University, Narathiwat, 96000, Thailand;

关键词: N-phenylthiourea;    triphenylphosphane;    silver(I)nitrate;    crystal structure;   

DOI  :  10.1107/S1600536814014147

来源: DOAJ

【 摘 要 】

In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the AgI atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H...O hydrogen bonds, generating tetramers (two cations and two anions), which feature R22(8) and R44(8) loops. The cations are linked by weak C—H...π interactions, generating a three-dimensional network.

【 授权许可】

Unknown