Arene-Osmium(II) Complexes in Homogeneous Catalysis

Inorganics

Victorio Cadierno¹  Pascale Crochet¹ 

[1] Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Clavería 8, E-33006 Oviedo, Spain;

关键词: arene;    osmium;    half-sandwich complexes;    homogeneous catalysis;   

DOI  :  10.3390/inorganics9070055

来源: DOAJ

【 摘 要 】

Although the application of arene-osmium(II) complexes in homogeneous catalysis has been much less studied than that of their ruthenium analogues, different works have shown that, in some instances, a comparable or even superior effectiveness can be achieved with this particular class of compounds. This review article focuses on the catalytic applications of arene-osmium(II) complexes. Among others, transfer hydrogenation, hydrogenation, oxidation, and nitrile hydration reactions, as well as different C-C bond forming processes, are comprehensively discussed.

【 授权许可】

Unknown