Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane

Molecules

关键词: Radical;    iodane;    ether;    vinyl sulfone;    maleate;   

DOI  :  10.3390/10010195

来源: DOAJ

【 摘 要 】

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.

【 授权许可】

Unknown