Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane

Molecules

Takuya Sueda¹  Yasunori Takeuchi¹  Takashi Suefuji¹ 

[1] id="af1-molecules-10-00195">Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan, Tel. [phone], Fax [phone]

关键词: Radical;    iodine;    ether;    vinyl sulfone;    maleate;   

DOI  :  10.3390/10010195

来源: mdpi

【 摘 要 】

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.

【 授权许可】

Unknown   
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