Mechanism of Nano-Structuring Manipulation of the Crystallization Temperature of Superlattice-like [Ge8Sb92/Ge]3 Phase-Change Films

Nanomaterials

Yifeng Hu¹  Jiwei Zhai¹  Qingqian Qiu²  Pengzhi Wu²  Tianshu Lai² 

[1] Functional Material Research Laboratory, Tongji University, Shanghai 200092, China;State-Key Laboratory of Optoelectronic Materials and Technologies, School of Physics, Sun Yat-Sen University, Guangzhou 510275, China;

关键词: phase-change memory;    superlattice-like (SLL) structure;    coherent phonon spectroscopy;    stress;    Raman spectroscopy;   

DOI  :  10.3390/nano11010020

来源: DOAJ

【 摘 要 】

Superlattice-like (SLL) phase-change film is considered to be a promising phase-change material because it provides more controllabilities for the optimization of multiple performances of phase-change films. However, the mechanism by which SLL structure affects the properties of phase-change films is not well-understood. Here, four SLL phase-change films [Ge₈Sb₉₂(15 nm)/Ge (x nm)]₃ with different x are fabricated. Their behaviors of crystallization are investigated by measuring sheet resistance and coherent phonon spectroscopy, which show that the crystallization temperature (T_C) of these films increases anomalously with x, rather than decreases as the interfacial effects model predicted. A new stress effect is proposed to explain the anomalous increase in T_C with x. Raman spectroscopy reveals that Raman shifts of all phonon modes in SLL films deviate from their respective standard Raman shifts in stress-free crystalline films, confirming the presence of stress in SLL films. It is also shown that tensile and compressive stresses exist in Ge and Ge₈Sb₉₂ layers, respectively, which agrees with the lattice mismatch between the Ge and Ge₈Sb₉₂ constituent layers. It is also found that the stress reduces with increasing x. Such a thickness dependence of stress can be used to explain the increase in crystallization temperature of four SLL films with x according to stress-enhanced crystallization. Our results reveal a new mechanism to affect the crystallization behaviors of SLL phase-change films besides interfacial effect. Stress and interfacial effects actually coexist and compete in SLL films, which can be used to explain the reported anomalous change in crystallization temperature with the film thickness and cycle number of periods in SLL phase-change films.

【 授权许可】

Unknown