Molecular structure of novel heterobimetallic thiolate [Cu(PPh3)]4(ZnCl)2(SEt)6.6THF

Main Group Metal Chemistry

Kociok-Köhn Gabriele¹  Molloy Kieran C.¹  Sudlow Anna L.¹ 

[1] Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK;

关键词: copper;    heterobimetallic;    thiolate;    x-ray;    zinc;   

DOI  :  10.1515/mgmc-2015-0013

来源: DOAJ

【 摘 要 】

Heterobimetallic thiolate [Cu(PPh3)]4(ZnCl)2 (SEt)6 has been synthesised and characterised by X-ray crystallography as a THF solvate. It contains the first structurally characterised example of a CuI-S(R)-ZnII linkage and only the second species type to embody the CuI-S-ZnII triad.

【 授权许可】

Unknown