期刊论文详细信息
Molecules | |
The Heck Reaction Applied to 1,3- and 1,2-Unsaturated Derivatives, a Way towards Molecular Complexity | |
关键词: Mizoroki–Heck reaction; palladium; 1,2-dienes; 1,3-dienes; | |
DOI : 10.3390/molecules15042667 | |
来源: DOAJ |
【 摘 要 】
This review is an overview of the last ten years’ use of the Mizoroki–Heck coupling applied to 1,2- and 1,3-dienes. Since both these systems form π-allyl palladium intermediates in Pd(0) coupling, they show particular chemical behavior. Many examples of 1,2-dienes Heck reactions are presented. 1,2-Dienes are important substrates because of their high reactivity that makes them useful building blocks for the synthesis of biologically relevant structures.
【 授权许可】
Unknown