期刊论文详细信息
Heterocyclic communications
Oxidative reaction of 2-aminopyridine-3-sulfonyl chlorides with tertiary amines
article
Huiping Wei1  Gaigai Wang1  Binbin Li1  Jianjun Huang1  Haiyan Li1  Olga P. Pereshivko1  Vsevolod A. Peshkov1 
[1] College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Dushu Lake Campus
关键词: aerobic oxidation;    amines;    enamines;    Hinsberg reaction;    sulfonyl chlorides;   
DOI  :  10.1515/hc-2016-0102
学科分类:内科医学
来源: De Gruyter
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【 摘 要 】

2-Aminopyridine-3-sulfonyl chlorides undergo a reaction with tertiary amines in the presence of air to produce sulfonylethenamines. The 2-aminopyridine-3-sulfonyl chloride apparently plays a dual role in the process promoting the aerobic oxidation of the amine and electrophilically trapping the resulting enamine.

【 授权许可】

CC BY|CC BY-NC-ND   

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