期刊论文详细信息
Heterocyclic communications | |
Oxidative reaction of 2-aminopyridine-3-sulfonyl chlorides with tertiary amines | |
article | |
Huiping Wei1  Gaigai Wang1  Binbin Li1  Jianjun Huang1  Haiyan Li1  Olga P. Pereshivko1  Vsevolod A. Peshkov1  | |
[1] College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Dushu Lake Campus | |
关键词: aerobic oxidation; amines; enamines; Hinsberg reaction; sulfonyl chlorides; | |
DOI : 10.1515/hc-2016-0102 | |
学科分类:内科医学 | |
来源: De Gruyter | |
【 摘 要 】
2-Aminopyridine-3-sulfonyl chlorides undergo a reaction with tertiary amines in the presence of air to produce sulfonylethenamines. The 2-aminopyridine-3-sulfonyl chloride apparently plays a dual role in the process promoting the aerobic oxidation of the amine and electrophilically trapping the resulting enamine.
【 授权许可】
CC BY|CC BY-NC-ND
【 预 览 】
Files | Size | Format | View |
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RO202107200002364ZK.pdf | 200KB | download |