Enantioselective synthesis of (R)-isocarvone from (S)-perillaldehyde

Journal of the Brazilian Chemical Society

Douglas Gamba¹  Diego S. Pisoni¹  Jessé S. Da Costa¹  Cesar L. Petzhold¹  Antonio C. A. Borges¹  Marco A. Ceschi¹ 

[1] ,Universidade Federal do Rio Grande do Sul Instituto de Química Porto Alegre RS ,Brazil

关键词: isocarvone;    preparation;    perillaldehyde;    building block;    cyclohex-2-enone;   

DOI  :  10.1590/S0103-50532008000700007

来源: SciELO

【 摘 要 】

This work describes the enantioselective preparation of (R)-(+)-isocarvone, (S)-(-)-5-isopropenylcyclohex-2-enone and (S)-(-)-3-isopropenylcyclohexanone starting from (S)-(-)-perillaldehyde. These compounds hold the prospect of serving as useful chiral building blocks or intermediates in organic synthesis.

【 授权许可】

CC BY   
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