Enantioselective synthesis of (R)-isocarvone from (S)-perillaldehyde

Journal of the Brazilian Chemical Society

Petzhold, Cesar L.¹  Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil¹  Borges, Antonio C. A.¹  Costa, Jessé S. da¹  Ceschi, Marco A.¹  Gamba, Douglas¹  Pisoni, Diego S.¹ 

关键词: isocarvone;    preparation;    perillaldehyde;    building block;    cyclohex-2-enone;   

DOI  :  10.1590/S0103-50532008000700007

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

This work describes the enantioselective preparation of (R)-(+)-isocarvone, (S)-(-)-5-isopropenylcyclohex-2-enone and (S)-(-)-3-isopropenylcyclohexanone starting from (S)-(-)-perillaldehyde. These compounds hold the prospect of serving as useful chiral building blocks or intermediates in organic synthesis.

【 授权许可】

Unknown