Microwave-Accelerated or Conventionally Heated Iodination Reactions of Some Aromatic Amines, Using ortho-Periodic Acid as the Oxidant†

Molecules

Maciej Sosnowski²  Lech Skulski¹ 

[1] id="af1-molecules-09-00617">Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, 1 Banacha Street, PL 02-097 Warsaw, Polan

关键词: Monoiodinated arylamines;    arylamines;    ortho-periodic acid as oxidant;    microwave irradiation.;   

DOI  :  10.3390/90700617

来源: mdpi

【 摘 要 】

A fast and simple method for the oxidative iodination of some aromatic amines, either under microwave irradiation or conventional heating, is reported, using diiodine and ortho-periodic acid as the oxidant. The reactions were carried out in boiling CH₂Cl₂ solutions under a reflux condenser. For the microwave assisted reactions, the reaction times were always notably shortened, but the yields were usually less influenced as compared with the conventional method.

【 授权许可】

Unknown   
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