Heterogeneous Catalysis of Polyoxometalate Based Organic–Inorganic Hybrids

Materials

Yuanhang Ren²  Meiyin Wang²  Xueying Chen²  Bin Yue¹  Heyong He¹ 

[1] Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China;

关键词: polyoxometalates;    organic–inorganic hybrid;    single crystal;    heterogeneous;    catalysis;   

DOI  :  10.3390/ma8041545

来源: mdpi

【 摘 要 】

Organic–inorganic hybrid polyoxometalate (POM) compounds are a subset of materials with unique structures and physical/chemical properties. The combination of metal-organic coordination complexes with classical POMs not only provides a powerful way to gain multifarious new compounds but also affords a new method to modify and functionalize POMs. In parallel with the many reports on the synthesis and structure of new hybrid POM compounds, the application of these compounds for heterogeneous catalysis has also attracted considerable attention. The hybrid POM compounds show noteworthy catalytic performance in acid, oxidation, and even in asymmetric catalytic reactions. This review summarizes the design and synthesis of organic–inorganic hybrid POM compounds and particularly highlights their recent progress in heterogeneous catalysis.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.