Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

Acta Crystallographica Section E: Crystallographic Communications

卷:71

Vasyl Kinzhybalo¹  Adam Pietraszko¹  Tamara J. Lukianova¹ 

[1] Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okolna str. 2, PO Box 1410, 50-950 Wroclaw, Poland;

关键词: crystal structure;    polyoxidomolybdate;    Anderson-type anion;    organic–inorganic hybrid;   

DOI  :  10.1107/S2056989015019246

来源: DOAJ

【 摘 要 】

A new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIII ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of intermolecular N—H...O and O—H...O interactions between cations, POMs, sulfate anions and non-coordinating water molecules creates a three-dimensional network structure.

【 授权许可】

Unknown