Crystal Structures of Furazanes

Crystals

Thomas M. Klapötke¹  Philipp C. Schmid¹  Jörg Stierstorfer¹ 

关键词: X-ray;    energetic;    furazane;    nitrogen-rich salts;    nitramino;   

DOI  :  10.3390/cryst5040418

来源: mdpi

【 摘 要 】

Several nitrogen-rich salts of 3-nitramino-4-nitrofurazane and dinitraminoazoxyfurazane were synthesized and characterized by various spectroscopic methods. The crystal structures were determined by low temperature single crystal X-ray diffraction. Moreover the sensitivities toward thermal and mechanical stimuli were determined by differential thermal analysis (DTA) and BAM (Bundesanstalt für Materialforschung und -prüfung) methods. The standard enthalpies of formation were calculated for all compounds at the CBS-4M level of theory, and the energetic performance was predicted with the EXPLO5 V6.02 computer code.

【 授权许可】

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© 2015 by the authors; licensee MDPI, Basel, Switzerland.