Catalytic Behavior and Phase Composition Change of Iron Catalyst in Hydrogenation of Carbon Dioxide

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Jyh-Fu Lee¹  Chau-Shang Chang¹  Min-Dar Lee¹ 

[1] Department of Chemical Engineering, National Taiwan University

关键词: Hydrogenation;    Carbon Dioxide;    Iron Catalyst;    Phase Composition;    Mössbauer Spectroscopy;   

DOI  :  10.1252/jcej.23.130

来源: Maruzen Company Ltd

【 摘 要 】

References(17)Cited-By(17)Hydrogenation of CO2 was conducted on iron catalyst under various reaction conditions to explore the catalytic behavior and the change of bulk phase composition. It was found by the use of Mössbauer spectroscopy that the metallic iron phase was transformed to a mixture of magnetite and carbides progressively during the course of reaction. The formation of Fe3O4 phase became more favorable under conditions which led to a high H2O partial pressure on the catalyst bed. On the other hand, the carburization of iron catalyst was enhanced at higher temperature, with χ-Fe5C2 phase being predominant over θ-Fe3C phase. Due to the fact that H2O produced in the Fischer–Tropsch reaction also contributes to the equilibrium of the reverse water–gas shift reaction, the common product H2O of these two steps plays a major role in suppression of overall CO2 conversion level.

【 授权许可】

Unknown