Continuation Report

Jessop, Philip G.

University of California, Davis

关键词: Promoters;    Polymers;    Carbon Dioxide;    37 Inorganic, Organic, Physical And Analytical Chemistry;    Hydrogenation;   

DOI  :  10.2172/812536
RP-ID  :  DOE/ER14986-1
RP-ID  :  FG03-99ER14986
RP-ID  :  812536

美国|英语

来源: UNT Digital Library

【 摘 要 】

OAK B262 In the first 8 months of this grant, the PI and his team have developed new hydrogenation catalysts for CO2 fixation, screened a series of ligands for their ability to dissolve in CO2, and invented a new and environmentally benign system for recovering and recycling homogeneous catalysts using CO2 and liquid polymers. The team has also begun work on two projects: (a) the evaluation of the effect of secondary interactions between ligands and CO2 on the insertion of CO2 into M-H bonds, and (b) the design and testing of promoters or catalysts for the insertion of CO2 into C-H bonds. Ongoing research is primarily focusing on these last two projects.