New Tools for CO(2) Fixation by Homogeneous Catalysis.

Jessop, P. G.

Technical Information Center Oak Ridge Tennessee

关键词: Catalysts;    Hydrogenation;    Carbon dioxide fixation;    Polymers;    Promoters;   

RP-ID  :  DE2003812536

学科分类：工程和技术（综合）

美国|英语

来源: National Technical Reports Library

【 摘 要 】

OAK B262 In the first 8 months of this grant, the PI and his team have developed new hydrogenation catalysts for CO2 fixation, screened a series of ligands for their ability to dissolve in CO2, and invented a new and environmentally benign system for recovering and recycling homogeneous catalysts using CO2 and liquid polymers. The team has also begun work on two projects: (a) the evaluation of the effect of secondary interactions between ligands and CO2 on the insertion of CO2 into M-H bonds, and (b) the design and testing of promoters or catalysts for the insertion of CO2 into C-H bonds. Ongoing research is primarily focusing on these last two projects.