期刊论文详细信息
| Journal of the Brazilian Chemical Society | |
| Tribromoisocyanuric acid/triphenylphosphine: a new system for conversion of alcohols into alkyl bromides | |
| Andrade, Vitor S. C. de1 Mattos, Marcio C. S. de1 Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brazil1 | |
| 关键词: alcohols; alkyl bromides; tribromoisocyanuric acid; triphenylphosphine; | |
| DOI : 10.5935/0103-5053.20140055 | |
| 学科分类：化学（综合） | |
| 来源: SciELO | |
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【 摘 要 】
An efficient and facile method has been developed for the conversion of alcohols into alkyl bromides under neutral conditions using tribromoisocyanuric acid and triphenylphosphine (molar ratio 1.0:0.7:2.0, alcohol/tribromoisocyanuric acid/triphenylphosphine) in dichloromethane at room temperature. This method can be applied for the conversion of primary, secondary, benzylic and allylic alcohols, and their corresponding bromides are obtained in 67-82 % yield. Tertiary alcohols do not react under these conditions.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201912050582195ZK.pdf | 199KB |  download |
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