期刊论文详细信息
Journal of the Brazilian Chemical Society
NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes
Institute of Industrial Organic Chemistry, Warsaw, Poland1  Gołębiewski, W. Marek1  Gucma, Mirosław1  Krawczyk, Maria1 
关键词: 1;    3-dipolar cycloaddition;    norbornenes;    nitrile oxides;    2D NMR;   
DOI  :  10.5935/0103-5053.20130106
学科分类:化学(综合)
来源: SciELO
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【 摘 要 】

The 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D 1H and 13C nuclear magnetic resonance (NMR).

【 授权许可】

Unknown   

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