期刊论文详细信息
Journal of the Brazilian Chemical Society | |
NMR studies on 1,3-dipolar cycloaddition of nitrile oxides to norbornenes | |
Institute of Industrial Organic Chemistry, Warsaw, Poland1  Gołębiewski, W. Marek1  Gucma, Mirosław1  Krawczyk, Maria1  | |
关键词: 1; 3-dipolar cycloaddition; norbornenes; nitrile oxides; 2D NMR; | |
DOI : 10.5935/0103-5053.20130106 | |
学科分类:化学(综合) | |
来源: SciELO | |
【 摘 要 】
The 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D 1H and 13C nuclear magnetic resonance (NMR).
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912050581908ZK.pdf | 869KB | download |