期刊论文详细信息
| Journal of the Brazilian Chemical Society | |
| Novel chiral ionic liquid (CIL) assisted selectivity enhancement to (L)-proline catalyzed asymmetric aldol reactions | |
| Zhou, Xiaohai1 Zhang, Long1 Wuhan University1 Cheng, Gongzhen1 Luo, Huadong1 Zhang, Haibo1 | |
| 关键词: aldol reaction; asymmetric synthesis; chiral ionic liquids; chiral additive; | |
| DOI : 10.1590/S0103-50532011000900016 | |
| 学科分类：化学（综合） | |
| 来源: SciELO | |
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【 摘 要 】
A significant improvement of the chemical yields (up to 88%), stereoselectivity (> 99:1) and enantiomeric excesses (up to 98%) of (L)-proline catalyzed direct asymmetric aldol reaction was found when proline based chiral ionic liquids (CILs) were added as additives. Different ratios of DMSO/H2O as solvent and chiral ionic liquids (CILs) with chiral cations of different chain length were investigated.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201912050581431ZK.pdf | 4166KB |  download |
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