Reactions of a stable dialkylsilylene and their mechanisms

Journal of Chemical Sciences

Mitsuo Kira1 2¹ 

[1] Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan$$

关键词: Stable silylene;    mechanisms;    photoreaction;    addition;    insertion;    DFT.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

Various reactions for a stable dialkylsilylene, 2,2,5,5-tetrakis(trimethylsilyl)silacyclopentane-1,1-diyl (1), are summarized and their mechanisms are discussed. Silylene 1 isomerizes to the corresponding silaethene via the 1,2-trimethylsilyl migration. Reduction of 1 with alkali metals affords the corresponding radical anion 1.− with a relatively small 29Si hfs constant (2.99 mT) and a large g-factor (g = 2.0077) compared with those for trivalent silyl radicals. Photo-excitation of 1 generates the corresponding singlet excited state (11*) with the lifetime of 80.5 ns. The excited state reacts with C=C double bond compounds including benzene, naphthalene, and (𝐸)- and (𝑍)-2-butenes. Although the thermal reactions of 1 with haloalkanes occur via radical mechanisms, the insertion into O-H, Si-H and Si-Cl bonds proceeds concertedly via the threemembered cyclic transition states. The reaction of 1 with H2SiCl2 gives the Si-Cl insertion product exclusively, while the quantitative insertion to Si-H bond occurs when Me2SiHCl is used as a substrate. The origin of the rather unusual Si-H/Si-Cl selectivity is elucidated using DFT calculations. Silylene 1 adds to C=C, C≡C, and C=O 𝜋 bonds to afford the corresponding silacycles as stable compounds. The importance of the carbonyl silaylides during the reactions of silylenes with aldehydes and ketones is emphasized.

【 授权许可】

Unknown