期刊论文详细信息
Journal of Chemical Sciences | |
Metal-catalysed organic transformations in water: From bromination to polymerisation | |
Braja N Patra11  Manish Bhattacharjee1  | |
[1] Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302$$ | |
关键词: Aqueous medium; bromination; polymerisation; titanium; zirconium; vanadium.; | |
DOI : | |
来源: Indian Academy of Sciences | |
【 摘 要 】
Reaction of ð›¼,ð›½-unsaturated aromatic carboxylic acids with KBr and H2O2 in the presence of Na2MoO4$cdot$H2O in aqueous medium affords ð›½-bromo alkenes in high yields. Metallocene dichlorides, Cp2MCl2 (M = Ti, Zr, or V) catalyse polymerisation of olefins in aqueous medium to afford high molecular weight polymers with low molecular weight distribution.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912040507810ZK.pdf | 104KB | download |