Undeca­carbon­yl[(4-methyl­sulfanylphen­yl)di­phenyl­phosphane]triruthenium(0): crystal structure and Hirshfeld surface analysis

Acta Crystallographica Section E: Crystallographic Communications

Shawkataly, O. bin¹  Abdelnasir, H.M.H.²  Sirat, S.S.³  Jotani, M.M.⁴ 

[1] Chemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia;Department of Chemistry, Alzaiem Alazhari University, 1933, Khartoum, Sudan;Department of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380001, India;Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia

关键词: CRYSTAL STRUCTURE;    RUTHENIUM;    CLUSTER;    CARBONYL;    HIRSHFELD SURFACE ANALYSIS;   

DOI  :  10.1107/S2056989018006989

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand, PPh2(C6H4SMe-4); no Ru⋯S inter­actions are observed. The phosphane occupies an equatorial position and its proximity to an Ru—Ru edge results in the elongation of this bond with respect to the others [2.8933 (2) Å cf. 2.8575 (2) and 2.8594 (3) Å]. In the crystal, phenyl-C—H⋯O(carbon­yl) and carbonyl-O⋯O(carbon­yl) [2.817 (2) Å] inter­actions combine to form a supra­molecular chain propagating along [111]; the chains pack without directional inter­actions between them. The carbonyl-O⋯O(carbon­yl) and other weak contacts have an influence upon the Hirshfeld surfaces with O⋯H contacts making the greatest contribution, i.e. 37.4% cf. 15.8% for O⋯O and 15.6% for H⋯H contacts.

【 授权许可】

CC BY