Crystal structure of [1,2-bis­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ3-2,4,6-tri­methyl­phenyl­phosphin­idene)-triangulo-triruthenium

Acta Crystallographica Section E: Crystallographic Communications

Kakizawa, T.¹ 

[1]Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan

关键词: CRYSTAL STRUCTURE;    CLUSTER;    PHOSPHINE;    RUTHENIUM;   

DOI  :  10.1107/S2056989017007770

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3 core that is capped with a mesitylphosphin­idene ligand, μ3-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol­ecules in the asymmetric unit.

【 授权许可】

CC BY