Crystal structure of ruthenocenecarbo­nitrile

Acta Crystallographica Section E: Crystallographic Communications

Strehler, F.¹  Korb, M.⁴  Lang, H.⁵ 

[1] Technische Universitär Chemie, Anorganische Chemie, D-09107 Chemnitz, Germany;r Naturwissenschaften, Institut füt Chemnitz, Fakultät fü

关键词: CRYSTAL STRUCTURE;    RUTHENOCENE;    RUTHENOCENECARBONITRILE;    SANDWICH COMPOUND;    NITRILE;   

DOI  :  10.1107/S205698901500540X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The mol­ecular structure of ruthenocenecarbo­nitrile, [Ru(η5-C5H4C≡N)(η5-C5H5)], exhibits point group symmetry m, with the mirror plane bis­ecting the mol­ecule through the C≡N substituent. The RuII atom is slightly shifted from the η5-C5H4 centroid towards the C≡N substituent. In the crystal, mol­ecules are arranged in columns parallel to [100]. One-dimensional inter­molecular π–π inter­actions [3.363 (3) Å] between the C≡N carbon atom and one carbon of the cyclo­penta­dienyl ring of the overlaying mol­ecule are present.

【 授权许可】

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