Crystal structure of poly[di-μ-aqua-{5-[(1Z)-2-(4-chloro­phen­yl)-1-cyano­ethenyl]-1,2,3,4-tetra­zol-1-ido-κN1}sodium]

Acta Crystallographica Section E: Crystallographic Communications

Akkurt, M.¹  Mohamed, S.K.²  Albayati, M.R.³  Mague, J.T.⁴  El-Saghier, A.M.M.⁵ 

[1] Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt;Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England;Department of Chemistry, Faculty of Science, Sohag University, Sohag 82524, Egypt;Department of Chemistry, Tulane University, New Orleans, LA 70118, USA;Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey

关键词: CRYSTAL STRUCTURE;    SODIUM SALT;    TETRAZOLES;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015006325

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, [Na(C10H5ClN5)(H2O)2]n, infinite chains of [Na(H2O)2]+ cations having a diamond-shaped cross-section and running parallel to the b axis are formed. O—H⋯N hydrogen bonds to the anions generate layers parallel to (100) which have the chloro­benzene­cyano­ethenyl substituents protruding from both surfaces. The sodium ion makes a short contact of 2.4801 (13) Å with the N atom of the tetra­zolide ring which is syn to the cyano N atom.

【 授权许可】

CC BY