Poly[μ2-aqua-aqua­[μ3-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ3O,O′:S]sodium]

Acta Crystallographica Section E: Crystallographic Communications

Butcher, R.J.¹  Wikaira, J.²  Bhat, M.A.³  Jain, S.³  Srivastava, S.K.³ 

[1] Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA;Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, New Zealand;School of Studies in Chemistry, Jiwaji University, Gwalior 474 011, India

关键词: CRYSTAL STRUCTURE;    DITHIOCARBAMATE;    SODIUM SALT;    TWO-DIMENSIONAL POLYMERIC STRUCTURE;   

DOI  :  10.1107/S2056989016000657

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, [Na(C7H14NOS2)(H2O)2]n, the NaI cation is coordinated by five O atoms [Na—O = 2.3142 (11)–2.4677 (10) Å] from three aqua and two N-butyl-N-(2-hy­droxy­eth­yl)di­thio­carbamate (L) ligands and one S atom [Na—S = 3.0074 (6) Å] from a third L ligand in a highly distorted octa­hedral geometry. Two aqua ligands related by an inversion center bridge two NaI cations, and each L ligand coordinates three NaI cations, leading to a layered arrangement aligned parallel to the bc plane. Inter­molecular O—H⋯S hydrogen bonds are observed in the inner part of each polymeric layer; these are packed along the a axis and held together by weak van der Waals forces.

【 授权许可】

CC BY